Why is sea water salty? The answer lies in a fascinating interplay of geological processes, including land runoff and hydrothermal vents, all of which contribute to the ocean’s unique chemical composition. At WHY.EDU.VN, we’re dedicated to exploring these intriguing scientific questions, and providing easy-to-understand answers that everyone can appreciate. Learn about seawater composition, ocean salinity factors, and hydrothermal vent contributions to salty seas.
1. Understanding the Primary Source: Land Runoff
The journey of ocean saltiness begins on land. Rainwater, naturally slightly acidic, acts as a weathering agent on rocks. This erosion process releases ions, which are essentially charged atoms, from the rocks. These ions, including sodium, chloride, magnesium, and calcium, are then carried by rivers and streams towards the ocean. This continuous influx of dissolved minerals from land is a primary reason why the ocean is salty. The concentration of these salts increase over time, shaping ocean salinity.
1.1. The Role of Acid Rain in Weathering
Acid rain is a catalyst in breaking down rocks. Carbon dioxide in the atmosphere dissolves in rainwater, forming weak carbonic acid. This mildly acidic water reacts with minerals in rocks, dissolving them and releasing their constituent ions.
1.2. Transporting Ions to the Ocean
Rivers are the highways that transport these ions from land to the ocean. As rivers flow over various terrains, they continuously pick up more dissolved minerals, adding to their salt content. The Amazon, Congo, and Mississippi rivers, among others, play a significant role in this process.
1.3. Accumulation Over Time
The ocean is like a giant reservoir. Over millions of years, the continuous influx of dissolved ions from land has led to the accumulation of salts in seawater. While some ions are used by marine organisms, others remain, contributing to the overall salinity.
2. Unveiling Hydrothermal Vents: The Seafloor’s Contribution
Another significant source of salt in the ocean is hydrothermal vents. These vents are openings in the seafloor where seawater seeps into cracks, is heated by magma from the Earth’s core, and then expelled back into the ocean. This process results in a series of chemical reactions that significantly alter the composition of the water.
2.1. Seawater Circulation Through the Earth’s Crust
Ocean water seeps into the porous seafloor, penetrating deep into the Earth’s crust. As it descends, it encounters increasing temperatures due to the proximity of magma chambers.
2.2. Chemical Reactions at High Temperatures
The extreme heat near magma chambers drives a series of chemical reactions. The seawater loses oxygen, magnesium, and sulfates, while picking up metals such as iron, zinc, and copper from the surrounding rocks.
2.3. Release of Metals into the Ocean
The heated water, now rich in dissolved metals, is released through hydrothermal vents back into the ocean. This process contributes significantly to the ocean’s salt content and the presence of various minerals. Hydrothermal vents are a primary reason why sea water is salty.
3. Volcanic Eruptions: A Direct Infusion of Minerals
Underwater volcanic eruptions directly release minerals into the ocean. The molten rock from the Earth’s interior contains a variety of elements that dissolve in seawater, adding to its saltiness. Volcanic eruptions can alter seawater composition.
3.1. Release of Minerals from Magma
Magma is a complex mixture of molten rock, dissolved gases, and minerals. When a volcano erupts underwater, the magma comes into direct contact with seawater, releasing its mineral content.
3.2. Dissolution in Seawater
Many of the minerals released from magma are soluble in seawater, meaning they dissolve and become part of the ocean’s composition. This process directly increases the concentration of various ions in seawater.
3.3. Impact on Local Salinity
Volcanic eruptions can have a localized impact on salinity, increasing the salt content in the immediate vicinity of the eruption. Over time, these localized effects spread and contribute to the overall salinity of the ocean.
4. Salt Domes: Ancient Deposits of Salt
Salt domes are vast underground and undersea deposits of salt formed over geological timescales. These domes are common in many parts of the world, including the continental shelf of the northwestern Gulf of America. Erosion and dissolution of these salt domes contribute to the ocean’s saltiness.
4.1. Formation Over Geological Timescales
Salt domes form over millions of years through the accumulation and compression of salt deposits. These deposits often originate from the evaporation of ancient seas.
4.2. Location of Salt Domes
Salt domes are found in various regions around the world, both underground and undersea. They are particularly common in areas with a history of marine sedimentation and tectonic activity.
4.3. Contribution to Ocean Salinity
Over time, salt domes can be eroded by water currents or dissolved by seawater, releasing their salt content into the ocean. This process contributes to the overall salinity of the ocean, reinforcing why sea water is salty.
5. Major Ions in Seawater: Chloride and Sodium
Chloride and sodium are the two most prevalent ions in seawater, together making up approximately 85 percent of all dissolved ions. These ions are highly soluble and relatively unreactive, allowing them to accumulate in seawater over long periods.
5.1. Abundance of Chloride Ions
Chloride ions are the most abundant anions (negatively charged ions) in seawater. They are primarily derived from the weathering of rocks on land and from hydrothermal vents.
5.2. Abundance of Sodium Ions
Sodium ions are the most abundant cations (positively charged ions) in seawater. Like chloride ions, they are primarily derived from the weathering of rocks on land.
5.3. Formation of Sodium Chloride (Salt)
When seawater evaporates, chloride and sodium ions combine to form sodium chloride, commonly known as table salt. This is the primary reason why sea salt tastes salty.
6. Other Significant Ions: Magnesium and Sulfate
Magnesium and sulfate are the next most abundant ions in seawater, making up another 10 percent of the total dissolved ions. These ions also play important roles in marine chemistry and biology.
6.1. Role of Magnesium Ions
Magnesium ions are essential for various biological processes in marine organisms. They are also involved in the formation of certain types of marine sediments.
6.2. Role of Sulfate Ions
Sulfate ions are involved in the sulfur cycle in the ocean and are used by some marine organisms for energy production. They also contribute to the overall ionic balance of seawater.
6.3. Combined Impact on Salinity
While chloride and sodium ions dominate, magnesium and sulfate ions contribute significantly to the overall salinity and chemical composition of seawater, and explain why sea water is salty.
7. Factors Influencing Salinity: Temperature, Evaporation, and Precipitation
The salinity of seawater varies depending on several factors, including temperature, evaporation, and precipitation. These factors influence the concentration of salt in different regions of the ocean.
7.1. Temperature Effects
Temperature affects the solubility of salts in water. Warmer water can dissolve more salt than colder water. However, temperature also influences evaporation rates, which can increase salinity.
7.2. Evaporation Effects
Evaporation removes water from the ocean, leaving the salt behind. Areas with high evaporation rates, such as the subtropics, tend to have higher salinity.
7.3. Precipitation Effects
Precipitation, including rain and snow, adds fresh water to the ocean, diluting the salt concentration. Areas with high precipitation rates, such as the equator and the poles, tend to have lower salinity.
8. Regional Variations in Salinity: Equator, Poles, and Mid-Latitudes
Salinity varies significantly across different regions of the ocean. Salinity is generally low at the equator and at the poles and high at mid-latitudes. These variations are due to differences in temperature, evaporation, and precipitation patterns.
8.1. Low Salinity at the Equator
The equator experiences high precipitation rates and high river runoff, which dilutes the salt concentration in seawater.
8.2. Low Salinity at the Poles
The poles also experience low salinity due to high precipitation rates (in the form of snow) and the melting of ice, which adds fresh water to the ocean.
8.3. High Salinity at Mid-Latitudes
Mid-latitudes experience high evaporation rates and low precipitation rates, leading to higher salinity levels.
9. Average Salinity of Seawater: 35 Parts Per Thousand
The average salinity of seawater is about 35 parts per thousand. This means that approximately 3.5 percent of the weight of seawater comes from dissolved salts. However, salinity can range from less than 30 parts per thousand in some coastal areas to more than 40 parts per thousand in enclosed seas.
9.1. Measurement of Salinity
Salinity is typically measured using instruments called salinometers, which determine the conductivity of seawater. Conductivity is directly related to the concentration of dissolved salts.
9.2. Significance of Average Salinity
The average salinity of seawater is a key parameter in oceanography, influencing density, circulation patterns, and marine life distribution.
9.3. Variations from the Average
While the average salinity is 35 parts per thousand, there are significant regional variations due to differences in temperature, evaporation, precipitation, and river runoff.
10. The Role of Marine Organisms in Salinity Balance
Marine organisms play a role in maintaining the salinity balance of the ocean. Some organisms use dissolved ions for building their shells and skeletons, effectively removing these ions from seawater.
10.1. Shell Formation
Many marine organisms, such as shellfish and corals, use calcium and carbonate ions to build their shells and skeletons. This process removes these ions from seawater, contributing to salinity balance.
10.2. Biological Uptake of Ions
Other marine organisms take up dissolved ions for various biological processes, such as photosynthesis and respiration. This also helps to regulate the concentration of ions in seawater.
10.3. Overall Impact on Salinity
While marine organisms do remove some ions from seawater, their overall impact on salinity is relatively small compared to the primary sources of salt, such as land runoff and hydrothermal vents, and is why sea water is salty.
11. Saltwater Composition: A Detailed Breakdown
Understanding the saltwater composition involves looking at the different elements and their roles. Here’s a look into the detailed makeup:
Ion | Chemical Formula | Percentage by Weight | Primary Source | Role in Marine Ecosystem |
---|---|---|---|---|
Chloride | Cl- | 55% | Weathering of rocks, vents | Osmotic balance, food chain |
Sodium | Na+ | 30.6% | Weathering of rocks | Nerve function, fluid balance |
Sulfate | SO42- | 7.7% | Volcanoes, runoff | Protein synthesis, energy production |
Magnesium | Mg2+ | 3.7% | Weathering, hydrothermal vents | Enzyme function, chlorophyll |
Calcium | Ca2+ | 1.2% | Limestone dissolution | Shell formation, bone structure |
Potassium | K+ | 1.1% | Weathering of rocks | Nerve function, osmotic balance |
Bicarbonate | HCO3- | 0.4% | Atmosphere, runoff | pH buffering, carbon cycling |
Bromide | Br- | 0.2% | Volcanoes, salt deposits | Trace element, possible antioxidant |
12. Human Impact on Ocean Salinity
Human activities can influence ocean salinity. Climate change, deforestation, and industrial pollution can alter precipitation patterns, river runoff, and ocean currents, all of which can affect salinity levels.
12.1. Climate Change Effects
Climate change is causing changes in temperature, evaporation, and precipitation patterns, leading to regional variations in salinity. Melting glaciers and ice sheets are also adding fresh water to the ocean, reducing salinity in some areas.
12.2. Deforestation Effects
Deforestation can increase soil erosion and runoff, leading to higher concentrations of dissolved minerals in rivers and, ultimately, the ocean.
12.3. Industrial Pollution Effects
Industrial pollution can introduce various chemicals and pollutants into the ocean, some of which can affect salinity levels and marine ecosystems.
13. The Dead Sea: An Extreme Example of Salinity
The Dead Sea is an extreme example of salinity. With a salt concentration of over 30 percent, it is one of the saltiest bodies of water on Earth. The high salinity of the Dead Sea is due to high evaporation rates and low precipitation rates.
13.1. Causes of Extreme Salinity
The Dead Sea is located in a desert region with high temperatures and low rainfall. This leads to high evaporation rates and low freshwater input, resulting in extreme salinity.
13.2. Unique Ecosystem
The high salinity of the Dead Sea makes it inhospitable to most forms of life. Only a few specialized microorganisms can survive in these extreme conditions.
13.3. Human Use
Despite its extreme salinity, the Dead Sea is used for mineral extraction and tourism. People come from around the world to float in its highly buoyant waters.
14. The Baltic Sea: A Brackish Environment
The Baltic Sea is a brackish environment, meaning it has a salinity level between that of freshwater and seawater. The low salinity of the Baltic Sea is due to high river runoff and low evaporation rates.
14.1. Causes of Low Salinity
The Baltic Sea receives a large amount of freshwater from rivers and has relatively low evaporation rates. This leads to lower salinity levels compared to the open ocean.
14.2. Unique Ecosystem
The brackish environment of the Baltic Sea supports a unique ecosystem with species adapted to lower salinity levels.
14.3. Environmental Challenges
The Baltic Sea faces several environmental challenges, including pollution, eutrophication, and the introduction of invasive species.
15. Salinity and Ocean Currents
Salinity plays a crucial role in ocean currents. Differences in salinity and temperature create density gradients that drive thermohaline circulation, a global system of ocean currents that distributes heat around the planet.
15.1. Density Gradients
Denser water sinks, while less dense water rises. Salinity and temperature both affect the density of seawater. Colder and saltier water is denser than warmer and fresher water.
15.2. Thermohaline Circulation
Thermohaline circulation is driven by differences in density caused by variations in temperature (thermo) and salinity (haline). This circulation pattern plays a vital role in regulating global climate.
15.3. Impact on Climate
Ocean currents transport heat from the equator towards the poles, moderating temperatures and influencing weather patterns around the world. Changes in salinity can disrupt these currents and affect climate.
16. Salinity and Marine Life: Adaptations and Challenges
Salinity is a critical factor for marine life. Different species have different tolerances to salinity, and changes in salinity can affect their distribution, behavior, and survival.
16.1. Osmoregulation
Marine organisms must regulate the concentration of salt in their bodies to maintain osmotic balance. This process, called osmoregulation, requires energy and specialized adaptations.
16.2. Species-Specific Tolerances
Different species have different tolerances to salinity. Some species, such as euryhaline organisms, can tolerate a wide range of salinity, while others, such as stenohaline organisms, can only tolerate a narrow range.
16.3. Impact of Salinity Changes
Changes in salinity can stress marine organisms, affecting their growth, reproduction, and survival. Extreme changes in salinity can lead to mass mortality events.
17. Measuring Ocean Salinity: Techniques and Tools
Measuring ocean salinity is essential for monitoring ocean conditions and understanding climate change. Various techniques and tools are used to measure salinity, including salinometers, conductivity sensors, and satellite remote sensing.
17.1. Salinometers
Salinometers are instruments that measure the conductivity of seawater. Conductivity is directly related to the concentration of dissolved salts.
17.2. Conductivity Sensors
Conductivity sensors are used to measure salinity in situ, meaning they can be deployed in the ocean to take real-time measurements.
17.3. Satellite Remote Sensing
Satellites equipped with microwave radiometers can measure the salinity of the ocean surface from space. This provides a global view of salinity patterns and changes over time.
18. Salinity and Water Density: A Crucial Relationship
The relationship between salinity and water density is crucial in understanding ocean dynamics. Higher salinity increases water density, impacting ocean currents and marine habitats.
18.1. Density Stratification
Density stratification occurs when layers of water with different densities form in the ocean. This stratification can affect the mixing of nutrients and oxygen in the water column.
18.2. Overturning Circulation
In some regions, cold, salty water sinks to the bottom of the ocean, driving overturning circulation. This process is important for distributing heat and nutrients throughout the ocean.
18.3. Implications for Marine Life
Density stratification and overturning circulation can affect the distribution and abundance of marine life. Changes in these processes can have significant ecological consequences.
19. Understanding the Role of Evaporation in Sea Salinity
Evaporation is a critical process in the ocean, playing a vital role in maintaining salinity levels. High evaporation rates lead to increased salinity, especially in subtropical regions.
19.1. Evaporation Process
Evaporation is the process by which liquid water turns into water vapor. In the ocean, evaporation is driven by solar radiation and wind.
19.2. Effect on Salinity
When water evaporates from the ocean surface, the salt remains behind. This increases the concentration of salt in the remaining water, leading to higher salinity.
19.3. Regional Variations in Evaporation
Evaporation rates vary significantly across different regions of the ocean, depending on factors such as temperature, humidity, and wind speed.
20. Precipitation’s Counteracting Effect on Salinity
While evaporation increases salinity, precipitation has the opposite effect. Rainfall dilutes seawater, reducing salinity levels, particularly in equatorial and polar regions.
20.1. Precipitation Process
Precipitation is the process by which water falls from the atmosphere to the Earth’s surface in the form of rain, snow, sleet, or hail.
20.2. Effect on Salinity
When rain falls on the ocean surface, it adds fresh water, diluting the salt concentration and reducing salinity.
20.3. Regional Variations in Precipitation
Precipitation patterns vary significantly across different regions of the ocean, depending on factors such as latitude, prevailing winds, and ocean currents.
21. Desalination: Turning Seawater into Fresh Water
Desalination is the process of removing salt from seawater to produce fresh water. This technology is becoming increasingly important in regions facing water scarcity.
21.1. Desalination Methods
There are several methods of desalination, including distillation, reverse osmosis, and electrodialysis.
21.2. Distillation
Distillation involves heating seawater to produce steam, which is then condensed to produce fresh water.
21.3. Reverse Osmosis
Reverse osmosis involves forcing seawater through a semipermeable membrane that filters out salt ions.
22. The Impact of Melting Glaciers on Ocean Salinity
Melting glaciers are contributing to a decrease in ocean salinity in certain regions. This influx of fresh water can disrupt marine ecosystems and alter ocean currents.
22.1. Glacier Melt Process
Glaciers are large masses of ice that accumulate over long periods. As the climate warms, glaciers melt at an increasing rate.
22.2. Effect on Salinity
When glaciers melt, they release fresh water into the ocean, diluting the salt concentration and reducing salinity.
22.3. Regional Impact
The impact of melting glaciers on salinity is most pronounced in regions near glaciers, such as the Arctic and Antarctic.
23. Brine Pools: Highly Saline Underwater Lakes
Brine pools are highly saline underwater lakes found in some parts of the ocean. These pools have extremely high salt concentrations, making them inhospitable to most marine life.
23.1. Formation of Brine Pools
Brine pools form when highly saline water seeps from underground salt deposits into the ocean.
23.2. Unique Characteristics
Brine pools are denser than surrounding seawater, causing them to form distinct layers on the seafloor. They also have different chemical compositions and microbial communities compared to surrounding seawater.
23.3. Scientific Significance
Brine pools are of interest to scientists because they provide insights into extreme environments and the limits of life on Earth.
24. Estuaries: Mixing Zones of Fresh and Salt Water
Estuaries are coastal bodies of water where fresh water from rivers mixes with salt water from the ocean. These are dynamic environments with varying salinity levels.
24.1. Estuarine Environments
Estuaries are characterized by a gradient of salinity, ranging from freshwater near the river mouth to saltwater near the ocean.
24.2. Importance of Estuaries
Estuaries are important habitats for many marine and aquatic species. They also provide valuable ecosystem services, such as nutrient cycling and water filtration.
24.3. Challenges Facing Estuaries
Estuaries face several environmental challenges, including pollution, habitat loss, and climate change.
25. Haloclines: Sharp Salinity Gradients in the Ocean
Haloclines are sharp salinity gradients in the ocean. These gradients can affect the mixing of water and the distribution of marine life.
25.1. Formation of Haloclines
Haloclines form when layers of water with different salinity levels meet and do not mix readily.
25.2. Impact on Mixing
Haloclines can inhibit the mixing of water, preventing the transfer of nutrients and oxygen between layers.
25.3. Ecological Significance
Haloclines can create distinct habitats for different species, with some organisms adapted to high salinity and others adapted to low salinity.
26. The Salinity of the Great Salt Lake: A Landlocked Saline Lake
The Great Salt Lake in Utah is a landlocked saline lake with a salinity level much higher than that of the ocean. This high salinity is due to evaporation and the lack of an outlet.
26.1. Causes of High Salinity
The Great Salt Lake is located in a desert region with high evaporation rates and low precipitation rates. It also lacks an outlet, so salt accumulates over time.
26.2. Unique Ecosystem
The high salinity of the Great Salt Lake supports a unique ecosystem with species adapted to extreme conditions, such as brine shrimp and halophilic bacteria.
26.3. Human Uses
The Great Salt Lake is used for mineral extraction, recreation, and as a habitat for migratory birds.
27. Salinity’s Impact on Ocean Acidification
Salinity can influence ocean acidification. Increased salinity can slightly increase the buffering capacity of seawater, but the overall impact is complex and depends on various factors.
27.1. Ocean Acidification Process
Ocean acidification is the ongoing decrease in the pH of the Earth’s oceans, caused by the uptake of carbon dioxide (CO2) from the atmosphere.
27.2. Salinity’s Role
Salinity can affect the solubility of CO2 in seawater and the buffering capacity of the ocean, influencing the rate of acidification.
27.3. Overall Impact
While increased salinity can slightly increase buffering capacity, the overall impact of ocean acidification is primarily driven by increased CO2 levels.
28. Salinity and Coral Reef Health: A Delicate Balance
Coral reefs are sensitive to changes in salinity. Extreme salinity fluctuations can stress corals and lead to bleaching, affecting their overall health and survival.
28.1. Coral Reef Ecosystems
Coral reefs are diverse and productive ecosystems that support a wide range of marine life.
28.2. Salinity Sensitivity
Corals thrive in stable salinity conditions. Extreme fluctuations can disrupt their osmotic balance and lead to bleaching.
28.3. Conservation Efforts
Protecting coral reefs from salinity stress requires managing coastal development, reducing pollution, and mitigating climate change.
29. Practical Applications: Monitoring Salinity for Weather Prediction
Monitoring salinity is important for weather prediction. Salinity influences ocean currents and sea surface temperature, which in turn affect weather patterns.
29.1. Role of Salinity in Weather
Salinity affects ocean density, currents, and sea surface temperature, all of which influence weather patterns.
29.2. Monitoring Techniques
Salinity is monitored using a variety of techniques, including satellite remote sensing, in situ sensors, and ocean buoys.
29.3. Predictive Models
Salinity data is incorporated into weather prediction models to improve the accuracy of forecasts.
30. Future Trends: Predicting Salinity Changes in a Changing Climate
Predicting salinity changes in a changing climate is a major challenge. Climate models suggest that salinity patterns will continue to shift, with some regions becoming saltier and others becoming fresher.
30.1. Climate Models
Climate models are used to simulate the Earth’s climate system and project future changes, including salinity patterns.
30.2. Projected Changes
Climate models predict that some regions will become saltier due to increased evaporation, while others will become fresher due to increased precipitation and glacier melt.
30.3. Implications for Marine Ecosystems
Projected salinity changes could have significant implications for marine ecosystems, affecting the distribution, behavior, and survival of many species.
FAQ: Unveiling More About Sea Salinity
Question | Answer |
---|---|
What makes sea water salty? | Sea water is salty due to the accumulation of dissolved salts from land runoff, hydrothermal vents, and volcanic eruptions. |
What are the main salts found in sea water? | The main salts in sea water are chloride and sodium, which make up about 85% of all dissolved salts. Other significant salts include magnesium and sulfate. |
How does evaporation affect sea water salinity? | Evaporation increases sea water salinity by removing water and leaving the salts behind, concentrating them in the remaining water. |
Why is the Dead Sea so salty? | The Dead Sea is extremely salty because it is located in a desert region with high evaporation rates and low precipitation, leading to a high concentration of salt. |
What role do rivers play in making the sea salty? | Rivers carry dissolved salts from land to the ocean, contributing to the accumulation of salts in sea water over time. |
How do hydrothermal vents contribute to ocean salinity? | Hydrothermal vents release minerals and metals into the ocean from the Earth’s crust, contributing to the salt content of sea water. |
Does melting ice affect sea water salinity? | Yes, melting ice from glaciers and ice sheets adds fresh water to the ocean, which can decrease sea water salinity in certain regions. |
How do marine organisms affect sea water salinity? | Marine organisms can remove some dissolved ions from sea water to build their shells and skeletons, but their overall impact on salinity is relatively small. |
What is the average salinity of the ocean? | The average salinity of the ocean is about 35 parts per thousand, meaning that about 3.5% of sea water is made up of dissolved salts. |
How does climate change affect ocean salinity? | Climate change can alter precipitation patterns, evaporation rates, and glacier melting, all of which can affect ocean salinity. Some regions are becoming saltier, while others are becoming fresher. |
Why is salinity important for marine life? | Salinity is crucial for marine life as different species have different tolerances to salinity levels. Changes in salinity can affect their distribution, behavior, and survival, and is why maintaining salinity balance is critical for marine ecosystems. |
How do scientists measure ocean salinity? | Scientists use various tools to measure salinity, including salinometers, conductivity sensors, and satellite remote sensing, which help monitor and understand salinity patterns. |
Can humans make fresh water from sea water? | Yes, through desalination processes such as distillation and reverse osmosis, sea water can be turned into fresh water, addressing water scarcity issues in some regions. |
What are brine pools, and how do they form? | Brine pools are highly saline underwater lakes that form when extremely salty water seeps from underground salt deposits into the ocean. They are unique environments with specialized microbial communities. |
Why does salinity vary in different parts of the ocean? | Salinity varies due to differences in temperature, evaporation, precipitation, and river runoff, leading to regional variations in salinity across the ocean. |
Understanding why sea water is salty requires knowledge of various geological and environmental processes, and WHY.EDU.VN is dedicated to providing you with that knowledge in an accessible and engaging way. We hope this comprehensive explanation has quenched your curiosity and given you a deeper appreciation for the ocean’s complex chemistry.
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